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Example of foreign carbon in pulp plant - South African Pres

2020-10-27 10:32

Introduction:Example of foreign c arbon in pulp plant - South African President Brand baking sand carbon in pulp plant This plantdeals with roasted sand.The production scale is 900 ~ 1000t/d, thefinenessof baking sand is 95-200 mesh, containing 10 ~ 12

Example of foreign carbon in pulp plant - South African President Brand baking sand carbon in pulp plant

This plant deals with roasted sand.The production scale is 900 ~ 1000t/d, thefineness of baking sand is 95-200 mesh, containing 10 ~ 12g/t of gold.Completed and put into operation in August 1980, it is the first large carbon in pulp plant in South Africa.The successful experience of this plant has played a positive role in promoting the wide application of carbon in pulp process in South Africa.
Process description:
The leaching tank is 4 Paduka tanks, and the leaching conditions are shown in table 9.1-1.The cyanide used in this plant is Ca(CN)2 and the single consumption is 0.7kg.The leaching rate was 83% ~ 88%.
Table 9.1-1 leaching conditions at President Brand baking carbon in pulp plant

Leaching conditions actual numerical
siurry density /t·m-1
Slurry concentration (solid)/%
Leaching time /h
pH value
temperature /℃
 
Cyanide concentration /%
Calcium oxide concentration /%
1.46~1.54
50
6~7
10.0
In the summer 30~35
In the winter 20~25
initial 0.04
last 0.038
0.01~0.017
Adsorption tanks were 7  Φ 5.6 x 5.6 m flat bottom tanks, volume of each120 m3, were lined with120 degrees configuration each other.The final carbon concentration was 40g/L, and the rest was 24g/L.Carbon stock 22.08 tons.The air hoist is used to move the carbon forward, and the carbon extraction speed is 1.5tons per day.Activated carbon is a french-made G210AS6 x 16 carbon with a loading capacity of 6000 ~ 7000g/t.The tailings can be reduced to below 0.03g/m3 with an adsorption rate of 99.5%.The plant found that there were two types of ions in the slurry, including Fe, Cu, Co, Ni and Mg, which could be adsorbed on activated carbon and compete with gold and silver for the adsorption position. The second type included CaSO4, complex sulfate, CaCO3, base metal carbonate, SiO2 and superfine baked sand particles.They tend to deposit clumps on the carbon and block its pores.These substances need to be soaked with 38% hydrochloric acid or rinsed with 10% hot hydrochloric acid to remove them.
The desorption process adopts AARL process.Pretreatment: with5% NaCN + 1% NaOH solution at 90 ℃ for 30 minutes to gold-loaded carbon.Desorption: with three times the carbon bed volume of soft water desorption 1.5 h, the temperature is 110 ℃.
Pickling is done in the desorption column before desorption work begins.Use twice the carbon bed size, the concentration of 3% dilute hydrochloric acid under the temperature of 90 ℃.The existing problem is that the CO2 generated by the reaction fluidizes the carbon particles and transports the carbon to the top of the desorption column, causing blockage of the outlet screen and increase of the desorption column pressure.
Carbon regeneration is carried out in a Wellman regeneration kiln heated by electricity.The length of regenerative kiln is 9.0m, the length of heating zone is 4 ~ 5m, and the length of cooling zone is 3 ~ 4 m.Heating zone temperature control at 700 ℃, the discharge of carbon regeneration temperature is 150 ℃.It is cooled by air from the outside.Carbon regeneration time is 20 minutes.
The electrodeposition loop includes 3  AARL shaped deposition tanks made of polyvinyl chloride, two working and one standby.Process pregnant solution 13 ~ 18m3 per day.A Dupont NAFION 420 cation exchange membrane is arranged between the cathode and the anode of the deposition tank.About 40% ~ 50% of cyanide in the cathode can be regenerated and returned to the leaching circuit for use.The anode electrolyte used contains NaOH 20%-25%, and the electroproduct parameters are shown in table 9.1-2.
Table 9.1-2. electrodeposition parameters of President Brand baking sand and carbon in pulp plant

parameters unit Design value actual numerical
Pregnant solution grade
Barren solution grade
recovery rate
flow
Cathode solution temperature
Anode solution concentration
electric current intensity
Cell voltage
electrodeposition time
g/m3
g/m3
%
m3/h

%
A
V
h
900
20
97.8
4.8
50
25~30
 
 
24
716.4
21.8
97.0
3.8
50
24
180
5.2
16
 
The cathode steel wool from the electrodeposition tank is dried and then mixed with borax to be smelted in induction furnace.



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